Using modeling to select catalyst dilution methods for mass transfer intensification in lab gas–liquid fixed-bed reactors

Electron-transfer-initiated benzoin- and Stetter-like reactions in packed-bed reactors for process intensification

A convenient heterogeneous continuous-flow procedure for the polarity reversal of aromatic α-diketones is presented. Propaedeutic batch experiments have been initially performed to select the optimal supported base capable to initiate the two electron-transfer process from the carbamoyl anion of the N,N-dimethylformamide (DMF) solvent to the α-diketone and generate the corresponding enediolate ...

High-fidelity DEM-CFD modeling of packed bed reactors for process intensification

A high-fidelity DEM-CFD model is newly proposed for process intensification of packed bed reactors. The discrete element method (DEM) is employed for simulating random packing under gravity with hundreds of spheres in a cylindrical tube. It is verified that the DEM is capable of constituting a packed bed whose voidage well agrees with the literature according to particle-to-tube diameter ratio....

Heat and Mass Transfer in Fixed-bed Tubular Reactor

Heat and mass transfer problem in a fixed-bed tubular reactor is one of the major concerns in the chemical engineering. The two dimensional axial plug flow model was used for a water gas shift reactor to compare heat conduction or mass diffusion with convective effect. In the case of fast fluid flow in highly permeable catalyst-bed, convective heat transfer was dominant compared to heat conduct...

24 Fixed Film Stationary Bed and Fluidized Bed Reactors

Rigorous Modeling of Fixed-Bed Reactors Containing Finite Hollow Cylindrical Catalyst with Michaelis-Menten Type of Kinetics

A large number of chemical, bio-chemical and pollution-control processes use heterogeneous fixed-bed reactors. The use of finite hollow cylindrical catalyst pellets can enhance conversion levels in such reactors. The absence of the pellet core can significantly lower the diffusional resistance associated with the solid phase. This leads to a better utilization of the catalytic material, which i...